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Die Synthese von Aldehyden und Ketonen mit Amidchloriden und V ILSMEIER ‐Reagenzien
Author(s) -
Bosshard H. H.,
Zollinger Hch.
Publication year - 1959
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19590420527
Subject(s) - chemistry , aldehyde , medicinal chemistry , amide , organic chemistry , catalysis
1 The constitution of amide chlorides and reaction products of amides with phosphoroxychloride is discussed. Based on infrared spectra and reaction behaviour an ionized constitution is proposed. 2 The mechanism of V ILSMEIER 's aldehyde synthesis is studied. Under certain conditions this reaction can be extended to the synthesis of ketones.