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Synthese von γ‐ L ‐Glutamyl‐hypoglycin A (Hypoglycin B)
Author(s) -
Jöhl A.,
Stoll W. G.
Publication year - 1959
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19590420311
Subject(s) - chemistry , stereochemistry , biochemistry
N‐TFA‐γ‐L‐glutamyl‐hypoglycin A α‐ethyl ester was prepared by coupling N‐TFA‐L‐glutamic acid α‐ethyl ester with hypoglycin A according to the mixed anhydride method, using isobutyl chlorocarbonate. After removal of the protecting groups the resulting γ‐ L ‐glutamyl‐hypoglycin A was found to be identical with natural hypoglycin B.