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Analyse des G IBBS 'schen Adsorptionstheorems
Author(s) -
de Witte Leendert
Publication year - 1959
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19590420229
Subject(s) - chemistry , extant taxon , relation (database) , thermodynamics , gibbs free energy , adsorption , physics , evolutionary biology , computer science , biology , database
The author has shown previously that three of the independent derivations of the GIBBS adsorption theorem, namely the ones by GOUY & MILNER, by GUGGENHEIM and by FOWLER & GUGGENHEIM, are invalid. It has also been shown that a totally different adsorption relation by J. J. THOMSON is extant and this relation has been extended to a completely general form. Finally it has been indicated that all remaining independent derivations have the starting relation and certain assumptions regarding this relation in common with the original GIBBS' derivation.