Veilchenriechstoffe. 62. Mitteilung. 1,1,4‐Trimethyl‐4‐[buten‐(4 1 )‐on‐(4 3 )]‐yl‐cyclohexen‐(2), ein weiteres Isomeres des α‐Jonons | Zendy

Re L. | Zendy; Schinz H. | Zendy

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Veilchenriechstoffe. 62. Mitteilung. 1,1,4‐Trimethyl‐4‐[buten‐(4 1 )‐on‐(4 3 )]‐yl‐cyclohexen‐(2), ein weiteres Isomeres des α‐Jonons

Author(s) -

Re L.,

Schinz H.

Publication year - 1958

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19580410625

Subject(s) - chemistry , aldehyde , acetone , ring (chemistry) , medicinal chemistry , condensation , side chain , stereochemistry , organic chemistry , catalysis , physics , polymer , thermodynamics

1,1,4‐Trimethyl‐4‐carbethoxy‐cyclohexan‐3‐ol, by loss of water in alkaline medium, gave 1,1,4‐trimethyl‐4‐carbethoxy‐cyclohex‐2‐ene which has been converted into the corresponding aldehyde. This latter compound, on condensation with acetone, gave 1,1,4‐trimethyl‐4‐(4 1 ‐buten‐4 3 ‐on)‐yl‐cyclohex‐2‐ene, a further isomer of α‐ionone, with both the isolated methyl group and the butenone side chain in position 4 of the ring.

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