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Photochemische Reaktionen. 1. Mitteilung. Lichtkatalysierte Dienon‐Phenol‐Umlagerung
Author(s) -
Dutler H.,
Bosshard H.,
Jeger O.
Publication year - 1957
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19570400230
Subject(s) - chemistry , phenols , phenol , organic chemistry , medicinal chemistry
Ultraviolet irradiation of Δ 1 ‐dehydro‐O‐acetyl‐testosterone (I) yields a mixture of ketonic and phenolic substances. Two of the phenols have been identified as 1‐methyl‐oestradiol‐17‐acetate (VIII) and 4‐methyl‐1‐hydroxy‐17 β‐acetoxy‐oestratriene‐(1,3,5:10) (X). A preliminary report is given on the nature of two additional phenolic products as well as of 4 ketones, isomeric with compound I.
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