Solvolyseversuche bei Verbindungen vom Typus des Δ 1,9 ‐10‐Hydroxymethyl‐octalins | Zendy

Rowe J. W. | Zendy; Melera A. | Zendy; Arigoni D. | Zendy; Jeger O. | Zendy; Ruzicka L. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Solvolyseversuche bei Verbindungen vom Typus des Δ 1,9 ‐10‐Hydroxymethyl‐octalins

Author(s) -

Rowe J. W.,

Melera A.,

Arigoni D.,

Jeger O.,

Ruzicka L.

Publication year - 1957

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19570400102

Subject(s) - solvolysis , chemistry , hydroxymethyl , bicyclic molecule , medicinal chemistry , stereochemistry , ring (chemistry) , hydrolysis , organic chemistry

Solvolysis of Δ 1,9 ‐10‐hydroxymethyl‐octaline benzenesulfonate (XIII) yields as the chief product [0,1,4,4]‐Δ 1 ‐tricyclo‐undecene (XV), the structure of which was subsequently proven by chemical means. In a competing reaction involving molecular rearrangement some bicyclic compound XVI is also found. Similarly Δ 12 ‐18, 28‐cyclo compounds have been isolated in the solvolysis of Δ 13,18 ‐28‐mesylates or benzenesulfonates of the oleanane series, thus supporting the view that homoallylic ring closure is the major reaction occurring in the solvolysis of compounds which contain the Δ 1,9 ‐10‐hydroxymethyl‐octaline system.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research