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Sesquiterpènes et azulènes. 121 e communication. Préparation et cyclisation du méthyl‐3‐allo‐cyclogéeranyl‐4‐butène‐2‐oïque
Author(s) -
Daesslé Cl.,
Schinz H.
Publication year - 1956
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19560390724
Subject(s) - bicyclic molecule , chemistry , stereochemistry , medicinal chemistry
Starting from allo‐cyclogeranic acid, 3‐methyl‐4‐allo‐cyclogeranylbut‐2‐ene‐oic acid has been prepared. This monocyclic compound has been converted into a bicyclic isomer, for which a spiroeyclic structure is assigned. It represents a further new type of synthetic bicyclic sesquiterpenes.