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Stabilität und Kinetik bei Komplexbildungsreaktionen. VI. Über das Verhalten des N,N‐Di‐n‐propyl‐dithiocarbamat‐Nickel Komplexes
Author(s) -
Bernauer K.,
Fallab S.,
Erlenmeyer H.
Publication year - 1956
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19560390712
Subject(s) - chemistry , thiocarbamate , dithiocarbamate , nickel , medicinal chemistry , dissociation (chemistry) , organic chemistry
The exchange reaction of Ni(II)N,N‐di‐propyl‐dithiocarbamate with Cu 2+ in methylcellosolve has been studied. The actual exchange reaction is much faster than the dissociation of the Ni(II)‐complex. It is therefore assumed that the metalion exchange is brought about through direct collision of Ni (II) NN‐ di‐propyl‐di thiocarbamate with cu 2+ .