Open AccessComparison of homofugality among alkyl groups attached to tin atom
Author(s) -
Kamimura Akio,
Yoshinaga Tatsuro,
Miyazaki Koichiro,
Kawamoto Takuji
Publication year - 2018
Publication title -
heteroatom chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.283
H-Index - 42
eISSN - 1098-1071
pISSN - 1042-7163
DOI - 10.1002/hc.21469
Subject(s) - chemistry , hydride , alkyl , tin , tributyltin hydride , enyne , medicinal chemistry , organic chemistry , catalysis , hydrogen
Dibutylmethyltin hydride and tert ‐butyldibutyltin hydride were employed to examine radical cascade reaction of aza‐1,6‐enyne for the preliminary estimation of homofugality between alkyl groups by product distribution analysis. Use of either dibutylmethyltin hydride or tert ‐butyldibutyltin hydride preferentially produced butylmethylstannolane, in which butyl group was mainly substituted by vinyl radical.