Physical modification of carbon nanotubes with a dendrimer bearing terminal mercaptoundecahydrododecaborates (Na 2 B 12 H 11 S) | Zendy

Yamagami Masahiro | Zendy; Tajima Tomoyuki | Zendy; Ishimoto Kango | Zendy; Miyake Hideaki | Zendy; Michiue Hiroyuki | Zendy; Takaguchi Yutaka | Zendy

Open Access

Physical modification of carbon nanotubes with a dendrimer bearing terminal mercaptoundecahydrododecaborates (Na 2 B 12 H 11 S)

Author(s) -

Yamagami Masahiro,

Tajima Tomoyuki,

Ishimoto Kango,

Miyake Hideaki,

Michiue Hiroyuki,

Takaguchi Yutaka

Publication year - 2018

Publication title -

heteroatom chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.283

H-Index - 42

eISSN - 1098-1071

pISSN - 1042-7163

DOI - 10.1002/hc.21467

Subject(s) - dendrimer , chemistry , boron , fluorescence , carbon nanotube , decane , amine gas treating , carbon fibers , nanotechnology , polymer chemistry , organic chemistry , materials science , composite number , composite material , physics , quantum mechanics

The thiol‐substituted B 12 ‐cluster mercaptoundecahydro‐ closo ‐dodecaborate Na 2 [B 12 H 11 SH ] ( BSH ) was successfully attached to a poly(amido)amine ( PAMAM ) dendrimer, which contains a bis(decyloxy)decane core. The physical modification of single‐walled carbon nanotubes ( SWCNT s) with dendrimer( SB 12 ) 4 afforded a SWCNT / dendrimer( SB 12 ) 4 nanohybrid that exhibited NIR ‐I‐to‐ NIR ‐ II fluorescence. Herein, we describe a promising strategy for in vivo imaging of boron clusters that may be widely applicable to boron neutron capture therapy.

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