Open AccessA green and mild procedure to selective synthesis of diarylamine via domino reaction of aryl halides and arginine catalyzed by magnetic‐ MOF
Author(s) -
SoleimanBeigi Mohammad,
Mohammadi Fariba
Publication year - 2018
Publication title -
heteroatom chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.283
H-Index - 42
eISSN - 1098-1071
pISSN - 1042-7163
DOI - 10.1002/hc.21450
Subject(s) - chemistry , reagent , aryl , catalysis , halide , domino , nitrogen , combinatorial chemistry , reaction conditions , organic chemistry , alkyl
Efficient and selective direct synthesis of diarylamines from aryl halides and arginine as a nitrogen‐donor reagent is reported. Arginine, which is an oral supplement, acts as a useful nitrogen source donor in the copper‐catalyzed reaction. Fe 3 O 4 /Cu 3 ( BTC ) 2 , which was easily separated and recycled with a magnet, improved the rate and facilitation of the synthesis of diarylamines selectively. The introduction of a new and available N‐source, simple magnetic separation process, normal atmospheric conditions, and excellent yields under mild reaction conditions are other important features of this work.