[1‐Me‐1‐ closo ‐SnB 11 H 11 ] −  as a potential weakly coordinating anion: Synthesis of Rh(PPh 3 ) 2 (1‐Me‐ closo ‐SnB 11 H 11 ) and comparisons with Rh(PR 3 ) 2  (1‐H‐ closo ‐CB 11  H 11 ) | Zendy

Molinos Eduardo | Zendy; Player Thomas P. H. | Zendy; KociokKöhn Gabriele | Zendy; Ruggerio Giuseppe D. | Zendy; Weller Andrew S. | Zendy

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[1‐Me‐1‐ closo ‐SnB 11 H 11 ] − as a potential weakly coordinating anion: Synthesis of Rh(PPh 3 ) 2 (1‐Me‐ closo ‐SnB 11 H 11 ) and comparisons with Rh(PR 3 ) 2 (1‐H‐ closo ‐CB 11 H 11 )

Author(s) -

Molinos Eduardo,

Player Thomas P. H.,

KociokKöhn Gabriele,

Ruggerio Giuseppe D.,

Weller Andrew S.

Publication year - 2006

Publication title -

heteroatom chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.283

H-Index - 42

eISSN - 1098-1071

pISSN - 1042-7163

DOI - 10.1002/hc.20218

Subject(s) - chemistry , heteroatom , ion , solid state , salt (chemistry) , crystallography , stereochemistry , medicinal chemistry , organic chemistry , ring (chemistry)

The closo ‐stannaborane salt [Rh(PPh 3 ) 2 ‐(nbd)][1‐Me‐1‐ closo ‐SnB 11 H 11 ] reacts with H 2 in CH 2 Cl 2 solution to afford the contact ion‐pair Rh(PPh 3 ) 2 (1‐Me‐ closo ‐SnB 11 H 11 ), which has been characterized in solution and the solid state by X‐ray diffraction. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:174–180, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20218

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