Interconversion of cyclotrimetallenes and dihalocyclotrimetallanes consisting of group 14 elements | Zendy

Ya. Lee Vladimir | Zendy; Matsuno Tadahiro | Zendy; Ichinohe Masaaki | Zendy; Sekiguchi Akira | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Interconversion of cyclotrimetallenes and dihalocyclotrimetallanes consisting of group 14 elements

Author(s) -

Ya. Lee Vladimir,

Matsuno Tadahiro,

Ichinohe Masaaki,

Sekiguchi Akira

Publication year - 2001

Publication title -

heteroatom chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.283

H-Index - 42

eISSN - 1098-1071

pISSN - 1042-7163

DOI - 10.1002/hc.1036

Subject(s) - chemistry , heteroatom , silylation , ring (chemistry) , carbon tetrachloride , group (periodic table) , chlorine atom , chlorine , medicinal chemistry , carbon fibers , stereochemistry , organic chemistry , catalysis , materials science , composite number , composite material

The 1‐ and 2‐disilagermirenes and cyclotrisilene were reacted with carbon tetrachloride or 1,2‐dibromoethane to give almost quantitatively the corresponding dihalocyclotrimetallane derivatives. The crystal structure of 1,2‐dichloro‐1,2,3,3‐tetrakis[di‐tert‐butyl(methyl)silyl]‐1,2‐disilagermirane showed a trans arrangement of the two chlorine atoms in the three‐membered ring system. Reduction of the dihalocyclotrimetallanes with t‐Bu 3 SiNa quantitatively produced the corresponding starting cyclotrimetallenes. © 2001 John Wiley & Sons, Inc. Heteroatom Chem 12:223–226, 2001

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research