A convenient one‐pot synthesis of 1,2‐azaphospholanium salts | Zendy

Aladzheva Inga M. | Zendy; Lobanov Dmitrii I. | Zendy; Bykhovskaya Ol'ga V. | Zendy; Petrovskii Pavel V. | Zendy; Lyssenko Konstantin A. | Zendy; Mastryukova Tatyana A. | Zendy

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A convenient one‐pot synthesis of 1,2‐azaphospholanium salts

Author(s) -

Aladzheva Inga M.,

Lobanov Dmitrii I.,

Bykhovskaya Ol'ga V.,

Petrovskii Pavel V.,

Lyssenko Konstantin A.,

Mastryukova Tatyana A.

Publication year - 2003

Publication title -

heteroatom chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.283

H-Index - 42

eISSN - 1098-1071

pISSN - 1042-7163

DOI - 10.1002/hc.10209

Subject(s) - chemistry , heteroatom , intramolecular force , alkylation , hydrolysis , phosphorus , organic chemistry , combinatorial chemistry , medicinal chemistry , catalysis , ring (chemistry)

A novel facile one‐pot synthesis of the 1,2‐azaphospholanes by intramolecular alkylation of 3‐halopropyl amides of tricoordinate phosphorus has been suggested. Using this method, a series of the differently N‐substituted 1,2‐azaphospholanium salts were synthesized. 3‐Aminopropylphosphine oxides were obtained by hydrolysis of the salts. A probable mechanism of the 1,2‐azaphospholanium salts formation is discussed. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:596–602, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10209

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