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Sulfur trioxide formation/emissions in coal‐fired air‐ and oxy‐fuel combustion processes: a review
Author(s) -
Sarbassov Yerbol,
Duan Lunbo,
Manovic Vasilije,
Anthony Edward J.
Publication year - 2018
Publication title -
greenhouse gases: science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.45
H-Index - 32
ISSN - 2152-3878
DOI - 10.1002/ghg.1767
Subject(s) - sulfur trioxide , flue gas , combustion , sulfur , sulfur dioxide , chemistry , oxy fuel , flue gas emissions from fossil fuel combustion , coal , waste management , sulfuric acid , coal combustion products , inorganic chemistry , organic chemistry , engineering
In oxy‐fuel combustion, fuel is burned using oxygen together with recycled flue gas, which is needed to control the combustion temperature. This leads to higher concentrations of sulfur dioxide and sulfur trioxide in the recycled gas, which can result in the formation of sulfuric acid and enhanced corrosion. Current experimental data on SO 3 formation, reaction mechanisms, and mathematical modelling have indicated significant differences in SO 3 formation between air‐ and oxy‐fuel combustion for both the wet and dry flue gas recycle options. This paper provides an extensive review of sulfur trioxide formation in air‐ and oxy‐fuel combustion environments, with an emphasis on coal‐fired systems. The first part summarizes recent findings on oxy‐fuel combustion experiments, as they affect sulfur trioxide formation. In the second part, the review focuses on sulfur trioxide formation mechanisms, and the influence of catalysis on sulfur trioxide formation. Finally, the current methods for measuring sulfur trioxide concentration are also reviewed along with the major difficulties associated with those measurements using data available from both bench‐ and pilot‐scale units. © 2018 Society of Chemical Industry and John Wiley & Sons, Ltd.