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Catalytic conversion of carbon dioxide to carboxylic acid derivatives
Author(s) -
Liu AnHua,
Yu Bing,
He LiangNian
Publication year - 2015
Publication title -
greenhouse gases: science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.45
H-Index - 32
ISSN - 2152-3878
DOI - 10.1002/ghg.1461
Subject(s) - carboxylation , catalysis , chemistry , carboxylic acid , organic chemistry , reagent , raw material , carbon dioxide , carbon fibers , halide , combinatorial chemistry , materials science , composite number , composite material
Chemical utilization of the greenhouse gas, i.e., CO 2 as an abundant, easily available, and renewable carbon feedstock for producing chemicals, materials, and fuels is attractive as an integral part of the carbon cycle. Based on the principle of CO 2 activation and elaborately designed catalysts, various transformation of CO 2 can be realized under mild conditions. In particular, establishing practical methodologies for catalytic carboxylation by CO 2 as carboxylative reagent would be a fascinating dream for synthetic chemists. This review covers the updated advances in the catalytic conversion of CO 2 into carboxylic acid derivatives from alkenes, alkynes, aromatic halides, aromatic C(sp 2 )‐H bonds, etc.
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