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A High‐Energy Density Li‐Ion Hybrid Capacitor Fabricated from Bio‐Waste Derived Carbon Nanosheets Cathode and Graphite Anode
Author(s) -
Nanaji Katchala,
Pappu Samhita,
Anandan Srinivasan,
Rao Tata N.
Publication year - 2022
Publication title -
global challenges
Language(s) - English
Resource type - Journals
ISSN - 2056-6646
DOI - 10.1002/gch2.202200082
Subject(s) - materials science , cathode , supercapacitor , anode , power density , energy storage , carbon fibers , capacitance , chemical engineering , crystallinity , potassium hydroxide , graphite , intercalation (chemistry) , electrode , nanotechnology , composite material , inorganic chemistry , electrical engineering , composite number , power (physics) , chemistry , engineering , physics , quantum mechanics
The Li‐ion hybrid capacitor (LIHC) system explores the possibility of achieving both high energy and power density in a single energy storage system with an intercalation anode and capacitive cathode. However, to achieve a high power and energy‐based system, the properties of the cathode electrode material are vital. Here, bio‐waste plant stem‐derived activated porous carbon is explored as a cathode for LIHC application. A specific surface area of 1826 m 2 g −1 , enhanced degree of crystallinity, and graphitization results for porous carbon from activation by potassium hydroxide. When employed as supercapacitor material, the device exhibits good rate capability, energy, and power attributes with a specific capacitance of 116 F g −1 (1 A g −1 ). Simultaneously when tested for LIHC application the formulated device shows good capacity retention for 2500 cycles with a high energy density of 125 Wh kg −1 at a power density of 69 W kg −1 . The work demonstrates unique, cost‐effective strategy to develop a crystalline high surface area carbon from any such bio‐waste sources to be employed as potential electrodes for energy storage applications.

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