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Morphology‐Controllable Synthesis and Growth Mechanism of 3D‐Hierarchical Pd/SnO 2 /Ni Foam (NF) as the Cathode for Al‐H 2 O 2 Semi‐Fuel Cell
Author(s) -
Sun L.,
Li S.,
He W.,
Wen F.
Publication year - 2019
Publication title -
fuel cells
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.485
H-Index - 69
eISSN - 1615-6854
pISSN - 1615-6846
DOI - 10.1002/fuce.201900020
Subject(s) - nanorod , materials science , nanoclusters , chemical engineering , nanomaterials , nanotechnology , electrochemistry , cathode , rutile , catalysis , morphology (biology) , nanostructure , nanoparticle , nanocrystal , composite number , electrode , specific surface area , composite material , chemistry , organic chemistry , engineering , biology , genetics
A hierarchical 3D composite cathode (Pd/SnO 2 /NF) was designed and synthesized via electrode positing Pd nanoparticles on the nanoarrays consisting of SnO 2 nanorods grown upright on the surface of Ni foam (NF). The influence of the adding rate of alcohol and the standing time of precursor on the morphology of SnO 2 nanostructures was investigated. The growth mechanism of SnO 2 nanorods was investigated and the influences of the morphology of SnO 2 nanomaterials on the size and electrochemical properties of Pd catalysts were also discussed. The morphology of SnO 2 nanomaterials changes from nanoclusters to nanorods, and both the diameters of the nanorods and Pd nanospheres decrease gradually with decreasing the adding rate of alcohol and prolonging the standing time of precursor. When the adding rate of alcohol is 0.022 mL s −1 and standing precursor for 15 min, the SnO 2 nanorods with a rutile structure are vertically grown on the surface of Ni foam apart, and Pd nanospheres are electrodeposited on the top of SnO 2 nanorods. The formation of hierarchical 3D structure is benefitting for fully exposing the active site of the Pd catalyst and increasing the specific surface area of the electrode, further improving the performance of the Al‐H 2 O 2 semi‐fuel cell.