Premium
Atmospheric Plasma Deposition: A New Pathway in the Design of Conducting Polymer‐Based Anodes for Hydrogen Fuel Cells
Author(s) -
Michel M.,
Bour J.,
Petersen J.,
Arnoult C.,
Ettingshausen F.,
Roth C.,
Ruch D.
Publication year - 2010
Publication title -
fuel cells
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.485
H-Index - 69
eISSN - 1615-6854
pISSN - 1615-6846
DOI - 10.1002/fuce.201000050
Subject(s) - materials science , chemical engineering , thin film , plasma polymerization , polyaniline , anode , hydrogen fuel , polymer , nucleation , nanotechnology , polymerization , chemistry , fuel cells , electrode , organic chemistry , composite material , engineering
In this study, we explored thin films of nanofibrous functionalised conducting plasma polyaniline (pPANI) with platinum deposited by an atmospheric plasma deposition process for the potential design of anodes for hydrogen fuel cell applications. We observed that the incorporation of such a polymer, characterised by both electronic and ionic conductivity, associated with a catalyst in a 3D porous network, could lead to an increased probability of the three‐phase contact to occur. In this context, aniline was mixed with functionalised platinum nanoparticles and used as the precursor. The role of these functionalised nanoparticles was not only to act as the catalyst for fuel cell purposes, but also as nucleation sites promoting the formation of the nanofibrous pPANI thin film during the plasma polymerisation. The morphology of the thin film was analysed by scanning electron microscopy and the efficiency, in terms of energy conversion, was assessed in a single fuel cell test bench.