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Methanol Tolerant Oxygen Reduction Catalysts Derived from Electrochemically Pre‐treated Bi 2 Pt 2–y Ir y O 7 Pyrochlores
Author(s) -
Beck N. K.,
Steiger B.,
Scherer G. G.,
Wokaun A.
Publication year - 2006
Publication title -
fuel cells
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.485
H-Index - 69
eISSN - 1615-6854
pISSN - 1615-6846
DOI - 10.1002/fuce.200500091
Subject(s) - pyrochlore , methanol , oxygen , chemistry , electrode , electrochemistry , materials science , inorganic chemistry , analytical chemistry (journal) , nuclear chemistry , organic chemistry , phase (matter) , chromatography
The electrocatalytic activity for oxygen reduction on Bi 2 Pt 2–y Ir y O 7 ( y = 0, 0.5, 1, 1.3, 1.4, 1.5, 2) electrodes was examined in 0.5 M H 2 SO 4 in the presence and absence of 0.5 M methanol, using the rotating ring‐disk electrode technique. These pyrochlore electrodes exhibited oxygen reduction activity with an onset potential at ca. 0.2 V vs. Hg/Hg 2 SO 4 only after pre‐treatment of potential cycling between –0.6 and 0.6 V vs. Hg/Hg 2 SO 4 . This “activation” of the pyrochlores is initiated by a reduction process that produces Bi 0 and Pt 0 at potentials located near the negative limit of the potential cycling range. Depending on the amount of pyrochlore used to fabricate the electrodes and the amount of charge passed during the reductive “activation”, a thick layer of a Pt containing material that differs from the pyrochlore structure may be produced. A pre‐treatment of potential cycling between –0.3 and 0.8 V vs. Hg/Hg 2 SO 4 did not “activate” the pyrochlores. The oxygen reduction activity and the methanol oxidation activity of the electrochemically treated pyrochlores increased in the order: Bi 2 Pt 0.5 Ir 1.5 O 7 < Bi 2 Pt 0.6 Ir 1.4 O 7 < Bi 2 Pt 0.7 Ir 1.3 O 7 < Bi 2 PtIrO 7 < Bi 2 Pt 1.5 Ir 0.5 O 7 < Bi 2 Pt 2 O 7 . Electrochemically treated Bi 2 Ir 2 O 7 exhibited no catalytic activity.