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On the Stability of Selected Monomeric and Polymeric Aryl Sulfonic Acids on Heating in Water (Part 1)
Author(s) -
Vogel C.,
MeierHaack J.,
Taeger A.,
Lehmann D.
Publication year - 2004
Publication title -
fuel cells
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.485
H-Index - 69
eISSN - 1615-6854
pISSN - 1615-6846
DOI - 10.1002/fuce.200400035
Subject(s) - sulfonic acid , aryl , sulfonamide , chemistry , monomer , styrene , polymer , thermal stability , organic chemistry , phthalimides , polymer chemistry , copolymer , alkyl , phthalimide
A number of low molecular weight sulfonated aromatic compounds: carboxamides, imides, sulfonamides, as well as sulfonated polymers; aramides and poly(styrene‐ p ‐sulfonic acid), were tested for their stability on heating in water and dilute acid to temperatures ranging from 130–200 °C. Desulfonation was observed with some compounds. Sulfonamide linkages were found to be stable, while carboxamide linkages and phthalimides were not.

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