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Improved gas chromatographic stereodifferentiation of chiral main constituents from different essential oils using a mixture of chiral stationary phases
Author(s) -
Bayer Mathias,
Mosandl Armin
Publication year - 2004
Publication title -
flavour and fragrance journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.393
H-Index - 70
eISSN - 1099-1026
pISSN - 0882-5734
DOI - 10.1002/ffj.1429
Subject(s) - chemistry , linalool , linalyl acetate , nerolidol , limonene , chromatography , essential oil , terpineol , enantioselective synthesis , lavender , monoterpene , organic chemistry , geraniol , gas chromatography , enantiomer , stationary phase , catalysis
The simultaneous enantioselective gas chromatographic differentiation of the chiral main compounds of lavender, neroli, petitgrain and bitter orange oil [limonene, linalool, linalool oxides (furanoid), linalyl acetate, ( E )‐nerolidol, α ‐pinene, β ‐pinene, terpinen‐4‐ol and α ‐terpineol] is described, using a dened mixture of heptakis(2,3‐di‐ O ‐methyl‐6‐ O ‐ tert ‐butyldimethylsilyl)‐ β ‐cyclodextrin and heptakis(2,3‐di‐ O ‐acetyl‐6‐ O ‐ tert ‐butyldimethylsilyl)‐ β ‐cyclodextrin as the chiral stationary phase. Copyright © 2004 John Wiley & Sons, Ltd.