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Solubilities and surface activities of phthalates investigated by surface tension measurements
Author(s) -
Thomsen Marianne,
Carlsen Lars,
Hvidt Søren
Publication year - 2001
Publication title -
environmental toxicology and chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.1
H-Index - 171
eISSN - 1552-8618
pISSN - 0730-7268
DOI - 10.1002/etc.5620200113
Subject(s) - surface tension , chemistry , solubility , adsorption , enthalpy , gibbs free energy , alkyl , aqueous solution , phthalate , standard molar entropy , dissolution , delta , surface energy , degree (music) , thermodynamics , organic chemistry , standard enthalpy of formation , physics , acoustics , engineering , aerospace engineering
Aueous solutions of DEP (di‐ethyl), DnBP (di‐ n ‐butyl), DnH(6)P (di‐ n ‐hexyl), and DEHP (di‐[2‐ethyl‐hexyl])phthalates have been investigated by use of surface tension measurements at temperatures between 10 and 35°C. A tensiometric approach allows for the determination of unimeric solubilities and Δ G °, which is the standard Gibbs free energy change, for the dissolution of phthalates in water. The unimeric solubility of the phthalates increase with decreasing temperature. The Δ G ° shows a linear increase with increasing phthalate alkyl chain length. The contribution of enthalpy (Δ H °) and entropy (Δ S °) to Δ G ° were calculated from the temperature‐dependent solubilities. The contributions of both Δ H ° and Δ S ° are negative and increase in magnitude with increasing alkyl chain length, suggesting hydrophobic interactions between phthalates and water. The ability of different phthalates to lower the surface tension decreases with increasing alkyl chain length, whereas the relative affinity for adsorption in the air‐water interface increases drastically for long‐chain phthalates. Despite the low surface activity of phthalates compared with that of common surfactants, they show significant affinity for adsorption in air‐water interfaces of natural surface waters. This property, combined with their low solubilities, may affect the fate of these compounds within the natural environment, because they form emulsions above unimeric saturation in aqueous media.