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Synthesis process and catalytic activity of Nb 2 O 5 hollow spheres for reversible hydrogen storage of MgH 2
Author(s) -
Zhang Xuelian,
Wang Ke,
Zhang Xin,
Hu Jianjiang,
Gao Mingxia,
Pan Hongge,
Liu Yongfeng
Publication year - 2021
Publication title -
international journal of energy research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.808
H-Index - 95
eISSN - 1099-114X
pISSN - 0363-907X
DOI - 10.1002/er.6006
Subject(s) - dehydrogenation , calcination , hydrogen storage , catalysis , hydrogen , kinetics , valence (chemistry) , chemical engineering , chemistry , materials science , inorganic chemistry , organic chemistry , physics , quantum mechanics , engineering
Summary High operation temperatures and slow reaction kinetics are major obstacles to use MgH 2 as a solid hydrogen store. We report here the synthesis of Nb 2 O 5 hollow spheres (o‐Nb 2 O 5 ) with wall thickness of approximately 50 nm and mossy surfaces using a facile hydrothermal and calcination process, which showed high activity in catalysis of MgH 2 for hydrogen storage. The dehydrogenation onset temperature of MgH 2 was decreased to 195°C with 7 wt% of o‐Nb 2 O 5 . More than 5.5 wt% H 2 can be desorbed at 300°C within 5 minutes. Hydrogen re‐absorption starts even at 25°C and reaches 5.6 wt% within 5 minutes at 200°C. Practical hydrogen capacity stabilizes at 5.8 wt% after 10 cycles of hydrogen uptake/release. The o‐Nb 2 O 5 was found to be reduced in situ by MgH 2 to low‐valence Nb species during the initial dehydrogenation process, which functions as an active catalyst and leads to the enhanced dehydrogenation kinetics.