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Electronic anti‐injection effect for carbonyl in anchor group based on diphenylacetylene D 2 ‐π‐A sensitizer in dye‐sensitized solar cells
Author(s) -
Chen Shaorui,
Pang Zhihan,
Wu Wenjun
Publication year - 2021
Publication title -
international journal of energy research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.808
H-Index - 95
eISSN - 1099-114X
pISSN - 0363-907X
DOI - 10.1002/er.5969
Subject(s) - cyanoacetic acid , chemistry , rhodanine , diphenylacetylene , acetic acid , intramolecular force , photochemistry , triphenylamine , furfural , molecule , energy conversion efficiency , organic chemistry , materials science , optoelectronics , catalysis
Summary Up to now, in developing organic molecules for dye‐sensitized solar cells, the determining role of acceptors has not yet received enough attention. Herein, three novel sensitizers were prepared with D 2 ‐π‐A structure, following cyanoacetic acid, acetic acid, and rhodanine‐3‐acetic acid as the acceptors, respectively. It was found that the thiocarbonyl and carbonyl groups, which are separated by two atoms with carboxyl group, effectively promoted molecular light harvesting, intramolecular charge transfer, and improved energy level matching, but a significant electron‐blocking effect occurred, which limited the enhancement of photoelectric conversion performance with rhodanine‐3‐acetic acid. From PT‐1 to PT‐3 , the power conversion efficiency decreased sharply from 5.27% to 2.70%. As a result, an electronic anti‐injection effect of electron‐drawing unit in the anchor group compared with cyanoacetic acid was found for the development of organic sensitizer design.