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Ordinary clay as a support of nickel catalyst for steam reforming of acetic acid: Impacts of pretreatments of clay on catalytic behaviors
Author(s) -
Gao Zhiran,
Zhang Zhanming,
Tian Hongli,
Xu Qing,
Xu Zhixiang,
Li Bin,
Liu Qing,
Li Cuncheng,
Chen Guozhu,
Hu Xun
Publication year - 2020
Publication title -
international journal of energy research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.808
H-Index - 95
eISSN - 1099-114X
pISSN - 0363-907X
DOI - 10.1002/er.5660
Subject(s) - catalysis , nickel , coke , acetic acid , leaching (pedology) , chemical engineering , chemistry , adsorption , materials science , inorganic chemistry , organic chemistry , geology , engineering , soil science , soil water
Summary Ordinary clay is a widely distributed and abundantly available material with the potential use as support of nickel catalysts with low cost. For the steam reforming of acetic acid, this study demonstrated the feasibility of ordinary clay as carrier of nickel catalyst. The pretreatment of the clay via impregnation with H 2 SO 4 , leaching with H 2 SO 4 and pretreated with NaOH were carried out and the results indicated the substantial influences on physiochemical properties and catalytic behaviors of the catalysts. The Ni/Clay‐NaOH catalyst contained the most developed porous structures due to the formation of the water soluble Na 4 SiO 4 by the solid‐phase reaction between the SiO 2 in clay and NaOH, which also rendered this catalyst with the superior catalytic activity. In addition, Ni/Clay‐NaOH catalyst also possessed the higher capability to gasify the reactive intermediates such as CCC and CO species as well as the CC species formed from the dissociative adsorption of acetic acid. This resulted in Ni/Clay‐NaOH catalyst with the highest resistivity toward coking. The varied treatment of the ordinary clay also was the reason of the coke formed with the distinct morphologies such as the amorphous coke with layered structure, the carbon‐nanotube form coke with single/multiple channels, defective structures, and varied sizes.