Premium
Evaluation of the performance and atmospheric emissions in a diesel engine of the biofuel obtained by hydrodeoxygenation of oleic acid with Pt/ γ‐Al 2 O 3 catalysts
Author(s) -
SánchezCárdenas Manuel,
SánchezOlmos Luis A.,
Kamaraj SathishKumar,
TrejoZarraga Fernando,
RodríguezValadez Francisco J.
Publication year - 2021
Publication title -
environmental progress and sustainable energy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.495
H-Index - 66
eISSN - 1944-7450
pISSN - 1944-7442
DOI - 10.1002/ep.13582
Subject(s) - hydrodeoxygenation , diesel fuel , oleic acid , biofuel , catalysis , vegetable oil refining , dispersion (optics) , biodiesel , chemistry , materials science , chemical engineering , organic chemistry , selectivity , waste management , physics , biochemistry , optics , engineering
Pt/γ‐Al 2 O 3 catalysts were prepared by incipient wet impregnation and tested in hydrodeoxygenation reactions for conversion of oleic acid to n‐C 17 alkanes at optimal conditions. The high conversion of 96.5% to renewable biodiesel (RD) is justified with the characterization results, showing that the catalyst has good texture properties, presence of metallic Pt evidenced by 2 θ reflections and binding energies, as well as adequate dispersion of active phase and nanoparticle size. 20% and 40% mixtures of RD with diesel were used. At full load a slight decrease in potency was observed when using RD mixtures and comparing them with petrodiesel; fortunately, the RD mixtures showed significant reductions in air pollutants, RD40 achieved reductions greater than 22% for CO, HC, and near 43% in emissions of smoke when compared to diesel.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom