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Applicability of various adsorption isotherm models on adsorption of methane and CO 2 on Indian shales
Author(s) -
Rani Sneha,
Prusty Basanta K.,
Padmanabhan Eswaran,
Pal Samir K.
Publication year - 2019
Publication title -
environmental progress and sustainable energy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.495
H-Index - 66
eISSN - 1944-7450
pISSN - 1944-7442
DOI - 10.1002/ep.13222
Subject(s) - methane , adsorption , oil shale , langmuir adsorption model , langmuir , chemistry , freundlich equation , thermodynamics , mineralogy , geology , organic chemistry , physics , paleontology
To produce natural gas (methane) and simultaneously sequester CO 2 in unconventional geologic reservoirs such as gas shale, coalbeds and so on, it is necessary to understand the adsorption behavior of methane and CO 2 in these reservoir formations. In this article, adsorption behavior of methane and CO 2 on shale samples from Gondwana Basin and KG Basin of India are studied. Adsorption experiments are conducted on as‐received shale samples from these basins at a temperature of 313 K to a maximum equilibrium pressure of approximately 9 MPa for methane and 6 MPa for CO 2 . The methane and CO 2 adsorption data are applied to test the applicability of Langmuir, Dubinin‐Polanyi, BET, and Ono‐Kondo models. A comparison of these models is performed using linear and nonlinear Chi‐squared methods. It was observed that Dubinin‐Astakhov equation was the most accurate adsorption isotherm model for adsorption of methane and CO 2 on tested shales. Further, the better fitting by Dubinin‐Polanyi equation over BET, Langmuir, and Ono‐Kondo models suggest that the mechanism of volume filling may be applicable during the adsorption of methane and CO 2 on shales. The preferential adsorption of methane and carbon dioxide on Pakur, KG, and Salanpur shales were investigated. The Pakur shale had CO 2 :CH 4 adsorption ratio ~1. © 2019 American Institute of Chemical Engineers Environ Prog, 38: 13222, 2019