Premium
Effects of phenolic antioxidants on biodiesel oxidative stability and emission
Author(s) -
Chen Peihong,
Wang Zhong,
Wu Jing,
Xia Hua,
Tai Chenxi,
Li Ruina
Publication year - 2019
Publication title -
environmental progress and sustainable energy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.495
H-Index - 66
eISSN - 1944-7450
pISSN - 1944-7442
DOI - 10.1002/ep.13203
Subject(s) - biodiesel , antioxidant , chemistry , nox , acid value , diesel fuel , food science , polyphenol , smoke , organic chemistry , biochemistry , combustion , catalysis
Biodiesel is a high‐quality diesel alternative fuel, but it can get easily oxidized on long‐term storage. The addition of antioxidants can effectively improve the oxidation stability of biodiesel. In this study, the mechanism of phenolic antioxidants to inhibit the oxidation of biodiesel and reduce the NO X emission is discussed based on the experimental investigation. Antioxidants (0.8 wt%) 3‐ tert ‐butyl‐4‐methoxyphenol (BHA), rosemary (K1), and tea polyphenols (K2) were added to biodiesel B100. The antioxidant test was carried out at atmospheric temperature for 4320 h, and the peroxide value, acid values were measured. Then, 0.8 wt% of K1, K2, and BHA were added to B20, named as K1B20, K2B20, and BHAB20. The 186F diesel engine bench test was carried out under 10%, 25%, 50%, 75%, and 100% load at 3000 rpm, with HC, CO, NO X , and smoke emissions of various types of fuel (B20, BHAB20, K1B20, and K2B20) were measured. The results of antioxidant test showed that the antioxidant effect of rosemary was best, displaying a decrease in acid and peroxide values by 25% and 48%, respectively. The diesel engine bench test results showed that antioxidants had little effect on HC, CO, and smoke emission; however, the antioxidants significantly reduced NO X emission. The effect of natural antioxidant rosemary to reduce NO X emission is the best one. At 3000 rpm and 75% load, the NOx of B20 reduced by 9.4%. Among the three antioxidants, the experimental results verified the mechanistic analysis and provided the basis for the selection of antioxidants for biodiesel. © 2019 American Institute of Chemical Engineers Environ Prog, 38:e13146, 2019