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Degradation of Alizarin Yellow R using UV/H 2 O 2 advanced oxidation process
Author(s) -
Narayanasamy Lavanyah,
Murugesan Thanapalan
Publication year - 2014
Publication title -
environmental progress and sustainable energy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.495
H-Index - 66
eISSN - 1944-7450
pISSN - 1944-7442
DOI - 10.1002/ep.11816
Subject(s) - degradation (telecommunications) , response surface methodology , hydrogen peroxide , alizarin , advanced oxidation process , kinetics , chemistry , nuclear chemistry , ultraviolet , chemical engineering , materials science , analytical chemistry (journal) , chromatography , catalysis , organic chemistry , computer science , telecommunications , physics , optoelectronics , quantum mechanics , engineering
The homogeneous advanced oxidation process of ultraviolet (UV) radiation in presence of hydrogen peroxide (H 2 O 2 ) was utilized to degrade Alizarin Yellow R, one of the most commonly used azo dyes in the textile industry. In this study, the effects of initial H 2 O 2 concentration, initial dye concentration, initial pH, and temperature were examined to determine the optimum conditions for maximum degradation. Complete degradation was achieved within 1 h, for all the experimental conditions studied in the present work. The Box–Behnken response surface methodology (RSM) was used for optimizing the variables of the degradation process. Based on the estimated optimum conditions, 92.7% of degradation was achieved. The degradation process was found to follow first order kinetics. The estimated rate constants, along with the optimized conditions will be of useful for the design and scale up of the combined UV/H 2 O 2 process for the said purpose. © 2013 American Institute of Chemical Engineers Environ Prog, 33: 482–489, 2014