Premium
Catalytic hydrotreatment of fast pyrolysis oil: Model studies on reaction pathways for the carbohydrate fraction
Author(s) -
Wildschut J.,
Arentz J.,
Rasrendra C.B.,
Venderbosch R.H.,
Heeres H.J.
Publication year - 2009
Publication title -
environmental progress and sustainable energy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.495
H-Index - 66
eISSN - 1944-7450
pISSN - 1944-7442
DOI - 10.1002/ep.10390
Subject(s) - catalysis , pyrolysis , chemistry , char , fraction (chemistry) , hydrocarbon , organic chemistry , pyrolysis oil , methane , chemical engineering , hydrogen , engineering
Fast pyrolysis oil can be upgraded by a catalytic hydrotreatment (250–400°C, 100–200 bar) using heterogeneous catalysts such as Ru/C to hydrocarbon‐like products that can serve as liquid transportation fuels. Insight into the complex reaction pathways of the various component fractions during hydrotreatment is desirable to reduce the formation of by‐products such as char and gaseous components. This paper deals with the catalytic hydrotreatment of representative model components for the carbohydrate fraction (viz., D ‐glucose and D ‐cellobiose) present in concentrations of 20–40% in fast pyrolysis oils. The hydrotreatment was conducted at a temperature of 250°C and 100 bar hydrogen using Ru and Pd on carbon catalysts in water. Two parallel reaction pathways are then observed, a thermal noncatalyzed pathway leading to insoluble humins (char) and a hydrogenation pathway leading to smaller polyols and gaseous hydrocarbons such as methane and ethane. The implications of these findings for the catalytic hydrotreatment of fast pyrolysis oil are discussed. © 2009 American Institute of Chemical Engineers Environ Prog, 2009