Open AccessAssembling metal‐polyphenol coordination interfaces for longstanding zinc metal anodes
Author(s) -
Huyan Yu,
Wang JianGan,
Tian Shan,
Ren Lingbo,
Liu Huanyan,
Wei Bingqing
Publication year - 2022
Publication title -
ecomat
Language(s) - English
Resource type - Journals
ISSN - 2567-3173
DOI - 10.1002/eom2.12173
Subject(s) - anode , nucleation , materials science , cathode , metal , coating , electrochemistry , tannic acid , galvanic anode , vanadium , zinc , corrosion , chemical engineering , battery (electricity) , metallurgy , chemistry , nanotechnology , electrode , cathodic protection , power (physics) , physics , organic chemistry , engineering , quantum mechanics
Zn metals have gained the immense attention of researchers for their wide employment as the anode of high‐performance aqueous batteries. Nonetheless, the Zn anodes suffer from uncontrollable dendrite growth and parasitic side reactions, which substantially shorten the battery lifespan. This study proposes an interfacial assembly of a metal‐polyphenol coordination coating on Zn anodes to regulate Zn 2+ deposition behavior. Bismush‐coordinated polyphenolic ligands (i.e., tannic acid, TA) create a functional interface that could promote Zn's uniform nucleation and plating/striping kinetics. Moreover, the artificial coating acts as a physical barrier to inhibit surface corrosion. As a consequence, the TA‐Bi‐modified Zn anodes display a small voltage hysteresis of ~38 mV at 1 mA cm −2 over 2600 h and an ultra‐long lifespan for 3100 h (~4.3 months) even at a high‐current density of 10 mA cm −2 . When assembled with a vanadium‐based cathode, the full Zn‐ion batteries achieve improved electrochemical performance.