Premium
Thermodynamic Guiding Principles for Designing Nonstoichiometric Redox Materials for Solar Thermochemical Fuel Production: Ceria, Perovskites, and Beyond
Author(s) -
Li Sha,
Wheeler Vincent M.,
Kumar Apurv,
Venkataraman Mahesh B.,
Muhich Christopher L.,
Hao Yong,
Lipiński Wojciech
Publication year - 2022
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.202270013
Subject(s) - redox , solar fuel , renewable energy , production (economics) , materials science , thermochemical cycle , nanotechnology , chemical engineering , chemistry , catalysis , metallurgy , hydrogen production , engineering , photocatalysis , organic chemistry , economics , electrical engineering , macroeconomics
Two‐step solar thermochemical water splitting is a promising pathway for renewable fuel production. Among the state‐of‐the‐art materials, ceria tends to favor the oxidation step while perovskites favor the reduction step and developing a champion material with well‐balanced redox thermodynamics remains a key challenge. A generic thermodynamic framework is thus presented to guide material design. More details can be found in article number 2000925 , Wojciech Lipiński and co‐workers.