Premium
Oxygen‐Doped Carbon Nitride Tubes for Highly Stable Lithium–Sulfur Batteries
Author(s) -
Ding Ling,
Lu Qiongqiong,
Permana Antonius Dimas Chandra,
Oswald Steffen,
Hantusch Martin,
Nielsch Kornelius,
Mikhailova Daria
Publication year - 2021
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.202001057
Subject(s) - polysulfide , sulfur , electrochemistry , nitride , carbon fibers , electrolyte , pyrolysis , chemistry , oxygen , redox , lithium (medication) , chemical engineering , inorganic chemistry , carbon nitride , materials science , catalysis , electrode , composite number , organic chemistry , medicine , layer (electronics) , photocatalysis , engineering , composite material , endocrinology
Graphitic carbon nitride g‐C 3 N 4 (GCN) has attracted extensive attention for electrochemical energy storage and conversion due to its high surface area, metal‐free characteristics, “earth‐abundance,” and facile synthesis. Furthermore, GCN has been demonstrated to exhibit a chemical interaction with polysulfides because of functional pyridinic nitrogen atoms, thus representing promising properties for application in lithium–sulfur (Li–S) batteries. Herein, an oxygen‐doped hexagonal tubular carbon nitride (O‐TCN) is obtained through a simple hydrolysis and pyrolysis approach. The tubular structure favors electrolyte infiltration and accommodates the volume change of sulfur during the redox reaction. Moreover, O‐TCN/S with a high content of pyridinic N of about 80 wt% as the sulfur host is beneficial for trapping various polysulfide intermediates via numerous strong N–Li chemical interactions, further facilitating the transformation from high‐order polysulfides to low‐order Li 2 S 2 or Li 2 S. As a result, O‐TCN delivers a high discharge capacity of 1281 mAh·g −1 at 0.05 C for the first cycle, and an excellent reversible capacity of 401 mAh g −1 after 1000 cycles at 0.5 C with an ultralow capacity decay of 0.064% per cycle, presenting a high sulfur utilization and capacity retention.