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Sequential Ultrasonic Spray‐Coating Planar Three Layers for 1 cm 2 Active Area Inverted Perovskite Solar Cells
Author(s) -
Chou Li-Hui,
Yu Yu-Tien,
Wang Xiao-Feng,
Osaka Itaru,
Wu Chun-Guey,
Liu Cheng-Liang
Publication year - 2020
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.202000216
Subject(s) - materials science , perovskite (structure) , coating , layer (electronics) , spin coating , non blocking i/o , deposition (geology) , energy conversion efficiency , perovskite solar cell , fabrication , photovoltaic system , chemical engineering , optoelectronics , nanotechnology , organic chemistry , catalysis , chemistry , medicine , paleontology , ecology , alternative medicine , pathology , sediment , engineering , biology
The sequential deposition of a NiO x hole‐transporting layer, one‐step CH 3 NH 3 PbI 3 perovskite absorber, and blended electron‐transporting layer that comprises [6,6]‐phenyl‐C 61 ‐butyric acid methyl ester (PCBM) and PNDI(2OD)T2 via automated ultrasonic spray‐coating technique is demonstrated in air for planar inverted p–i–n solution‐processed perovskite solar cells. Films fabricated via laboratory‐sale spin‐coating and industrially compatible spray‐coating process, respectively, are compared with each other to optimize both the film‐coating quality and corresponding device performance. This is validated by the photovoltaic performance of prototype devices with three spray‐coated layers with the active area of 1 × 1 cm 2 . The champion cells achieve a power conversion efficiency of 10.09%, which is one of the highest efficiencies obtained from fully spray‐processed large‐area perovskite solar cells thus far. Furthermore, these results reinforce the feasibility of the spray‐coating methodology for the fabrication of multilayers within perovskite solar cells stack and low‐cost route toward upscaling the manufacturing alternatives to spin coating.