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Construction of Dual‐Carbon Co‐Modified LiFePO 4 Nanocrystals via Microreactor Strategy for High‐Performance Lithium Ion Batteries
Author(s) -
Wang Bo,
Zhang Zekun,
Ning Yu,
Li Xinkui,
Ruan Tingting,
Wang Fei,
Wang Dianlong,
Zhou Yu
Publication year - 2020
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.202000171
Subject(s) - materials science , graphene , lithium (medication) , electrochemistry , carbon fibers , amorphous carbon , chemical engineering , battery (electricity) , nanotechnology , lithium iron phosphate , nanocomposite , cathode , lithium ion battery , amorphous solid , composite number , electrode , composite material , chemistry , organic chemistry , medicine , endocrinology , engineering , power (physics) , physics , quantum mechanics
A facile and controllable dual‐carbon microreactor approach has been developed to prepare graphene and amorphous carbon co‐decorated LiFePO 4 (LFP) nanocomposites (G/LFP@C). Physical characterizations demonstrate that the particle size of the restricted LFP crystals is ≈30–50 nm, which are well proportioned and well anchored on the surface of graphene and completely coated by the amorphous carbon layers. The electrochemical data demonstrate the impressive electrochemical performances of the G/LFP@C composite and its application potential as a cathode material of lithium ion batteries (LIBs). Particularly, the large specific capacity (161.3 mAh g −1 at 0.2 C), superior rate property (93.8 mAh g −1 at 20 C), and outstanding cycling stability (97.3% capacity retention over 1000 cycles at 10 C) are simultaneously realized for G/LFP@C because of the optimized electrochemical reaction kinetics with effective dual‐carbon co‐constructed conductive network and abundant active sites. It is believe that this work not only supplies unique in sights into the reasonable design of LFP materials for favorable property LIBs, but also holds great potential for the energy storage market.