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Prepotassiated V 2 O 5 as the Cathode Material for High‐Voltage Potassium‐Ion Batteries
Author(s) -
Yuan Kai,
Ning Ruiqi,
Bai Maohui,
Hu Nan,
Zhang Kun,
Gu Jinlei,
Li Qingyu,
Huang Youguo,
Shen Chao,
Xie Keyu
Publication year - 2020
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201900796
Subject(s) - cathode , materials science , ion , voltage , high voltage , potassium , electrode , analytical chemistry (journal) , chemistry , electrical engineering , metallurgy , organic chemistry , chromatography , engineering
The voltage and capacity of cathodes are critical factors for energy density of batteries. However, the cutoff voltage of cathode materials in potassium‐ion batteries (PIBs) is usually 4.0 V, causing structural transformations in the electrode materials in the course of repeated insertion/extraction of K + ions with a large radius (1.38 Å). Materials with large interlayer spacing and short ion diffusion paths show promise to overcome this issue. K 0.486 V 2 O 5 nanobelts, prepared by preinserting K + ions into V 2 O 5 , are used as cathode materials in high‐voltage PIBs. Various analysis methods are used to understand the insertion/extraction behavior of K + ions in K 0.486 V 2 O 5 cathodes cycled between 1.5 and 4.2 V. The analyses reveal the highly reversible structural evolution of K 0.486 V 2 O 5 , in which the chemically inserted K + ions partially remain between VO layers charged at high voltage serving as stabilizing species to prevent phase transformations. K 0.486 V 2 O 5 cathodes exhibit a high specific capacity of 159 mAh g −1 at 20 mA g −1 with good cycling stability of 67.4% after 100 cycles at 100 mAh g −1 in the half K‐ion cell. The results provide guidelines for designing layered transition metal oxides to be used as cathode materials for high‐voltage PIBs with high energy density.