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Compressed and Crumpled Porous Carbon Electrode for High Volumetric Performance Electrical Double‐Layer Capacitors
Author(s) -
Guo Hongshuai,
Ding Bing,
Dong Xiaowan,
Dong Shengyang,
Zhang Yadi,
Zhu Jiajia,
Dou Hui,
Zhang Xiaogang
Publication year - 2019
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201900209
Subject(s) - materials science , electrode , electrolyte , gravimetric analysis , carbon fibers , supercapacitor , chemical engineering , electrochemistry , cathode , specific surface area , capacitance , porosity , nanotechnology , diffusion , composite material , chemistry , organic chemistry , physics , composite number , engineering , thermodynamics , catalysis
The 2D carbon sheets have great potential for the construction of compact electrodes with high volumetric performance for electrical double‐layer capacitors (EDLCs), by virtue of their excellent electrical conductivity, high exposed surface area, free of interpores, and unimpeded ion‐diffusion channels. However, 2D nanosheets restack and aggregate during the preparation processes of electrodes, reducing available surface area, and limiting transport of ions. Herein, a facile and scalable method is presented to prepare highly porous crumple carbon balls (PCCBs) assembled by 2D carbon nanosheets. Such a unique nanostructure endows the PCCB electrode with large electrolyte‐accessible surface area and short ion‐diffusion pathways even when compressed at 40 MPa. Electrochemical evaluations in 1‐ethyl‐3‐methylimidazolium tetrafluoroborate (EMIMBF 4 ) electrolyte indicate that the compressed PCCB electrodes still show superior gravimetric (103 F g −1 ) and volumetric capacitances (127 F cm −3 ) at 1 A g −1 . The highest volumetric energy density of symmetrical EDLC based on compressed PCCB‐based electrode is 53.9 Wh L −1 . This work provides a new direction for the development of high volumetric energy density carbon‐based EDLCs.