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Intercalated Graphite between Ni Foam and Ni 3 S 2 Nanocrystals for the Activity Promotion in Overall Water Splitting
Author(s) -
Ma Biao,
Guo Xiaomeng,
Zhang Xiaopeng,
Chen Ying,
Fan Xiaobin,
Li Yang,
Zhang Fengbao,
Zhang Guoliang,
Peng Wenchao
Publication year - 2019
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201900063
Subject(s) - tafel equation , overpotential , water splitting , materials science , electrochemistry , electrode , anode , oxygen evolution , cathode , chemical engineering , nanotechnology , catalysis , chemistry , photocatalysis , organic chemistry , engineering
Herein, a novel 3D free‐standing electrode is synthesized, consisting of Ni 3 S 2 supported on a Ni foam (NF) with a graphite foam (GF) intercalated between them (Ni 3 S 2 @GF@NF). The hydrothermally synthesized Ni 3 S 2 has a hierarchical structure with abundant active sites exposed, and intimate interfacial contact can be formed during the in situ synthesis process. Moreover, the intercalated GF has a large surface area and good electric conductivity, which can create a new short route to facilitate electron transfer onto the active surface of Ni 3 S 2 . The Ni 3 S 2 @GF@NF electrode exhibits an excellent hydrogen evolution reaction performance with an early overpotential of 99 mV vs reversible hydrogen electrode at 10 mA cm −2 and a small Tafel slope of 98.2 mV dec −1 in alkaline solutions. However, the overpotential at 10 mA cm −2 and Tafel slope for the oxygen evolution reaction are 240 mV and 62.4 mV dec −1 in alkaline solutions. Using Ni 3 S 2 @GF@NF as both anode and cathode, only a small cell voltage of 1.63 V is needed to obtain 10 mA cm −2 for overall water splitting, comparable with the best free‐standing materials. Moreover, it exhibits a good stability due to the protection of GF. The free‐standing Ni 3 S 2 @GF@NF electrode contains no noble metals and should have a great potential in electrochemical water splitting.