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FeCl 3 Intercalated Microcrystalline Graphite Enables High Volumetric Capacity and Good Cycle Stability for Lithium‐Ion Batteries
Author(s) -
Sun Yali,
Han Fei,
Zhang Chengzhi,
Zhang Fuquan,
Zhou Dianwu,
Liu Hongbo,
Fan Changling,
Li Xuanke,
Liu Jinshui
Publication year - 2019
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201801091
Subject(s) - microcrystalline , graphite , gravimetric analysis , materials science , lithium (medication) , anode , chemical engineering , intercalation (chemistry) , carbon fibers , microstructure , electrode , inorganic chemistry , composite material , chemistry , composite number , organic chemistry , crystallography , medicine , engineering , endocrinology
To achieve a high volumetric capacity, both high tap density and high gravimetric capacity should be considered in one electrode. Herein, microcrystalline graphite (MG), a type of excellent graphite host, is proposed for the large‐scale preparation of FeCl 3 ‐intercalated graphite intercalation compounds (GICs) to simultaneously meet the requirements of high tap density (0.95 g cm −3 ) and high gravimetric capacity (905 mAh g −1 ). FeCl 3 ‐intercalated MG achieves the integration of isotropic orientation structure, amorphous carbon ingredients between graphite grains, and crumpled graphite layers, thus effectively buffering structure expansion and suppressing the dissolution of soluble FeCl 3 guest and LiCl discharge products. In a lithium‐ion cell, the anode shows a high volumetric capacity of 859 mAh cm −3 and a stable cycle performance for lithium‐ion storage. More importantly, the influence of microstructure features of GICs on their electrochemical properties is demonstrated, which may be of great value to better design and prepare other GIC anodes for high volumetric capacity and good cycle stability.