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A Dual‐Ion Battery with a Ferric Ferricyanide Anode Enabling Reversible Na + Intercalation
Author(s) -
Fan Jiaxin,
Fang Yaobing,
Xiao Qiangqiang,
Huang Runyu,
Li Li,
Yuan Wenhui
Publication year - 2019
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201800978
Subject(s) - faraday efficiency , anode , intercalation (chemistry) , materials science , cathode , cyclic voltammetry , ion , electrochemistry , battery (electricity) , inorganic chemistry , electrode , chemical engineering , chemistry , power (physics) , physics , organic chemistry , quantum mechanics , engineering
Dual‐ion batteries have been developed as a promising technology in recent years, but their high self‐discharge rate leading to low coulombic efficiency (CE) limits their practical applications. This work provides a deft strategy to circumvent this issue by using FeFe(CN) 6 as the anode material for hosting Na + cations, in combination with a graphite cathode for accommodating the bis (trifluoromethanesulfonyl)imide anions (TFSI − ). The relatively high bonding force between FeFe(CN) 6 and Na + can hinder self‐extraction of ions from the electrodes, thereby decreasing the self‐discharge rate. The FeFe(CN) 6 nanospheres, synthesized by a facile solution reaction method, are well crystallized and dispersed. Na + insertion into the FeFe(CN) 6 cube is determined by cyclic voltammetry (CV), galvanostatic charge–discharge, and X‐ray diffraction tests, suggesting a reversible process. Under a current of 0.05 mA cm −2 the batteries present an acceptable discharge plateau within 1.5–0.7 V and a well‐defined capacity of 75.0 mAh g −1 , with a high CE above 98.5% (±0.1%); under 0.2 mA cm −2 , cells display a high cyclability of 83.0% capacity retention for 100 cycles, with an excellent CE exceeding 99.6% (±0.1%). Moreover, the batteries exhibit a low self‐discharge rate with a resting capacity decay of 0.32% h −1 , outperforming many of the reported dual‐ion cells.