Premium
3D‐Printed, Carbon‐Nanotube‐Wrapped, Thermoresponsive Polymer Spheres for Safer Lithium‐Ion Batteries
Author(s) -
Huang Zhi Xiang,
Sim Glenn Joey,
Tan Jeck Chuang,
Low Hong Yee,
Yang Hui Ying
Publication year - 2018
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201700858
Subject(s) - thermal runaway , materials science , overheating (electricity) , carbon nanotube , nanotechnology , lithium (medication) , polymer , nanotube , electrode , composite material , battery (electricity) , chemistry , medicine , power (physics) , physics , quantum mechanics , endocrinology
Safety of lithium‐ion batteries (LIBs) has persistently plagued their development, despite widespread commercialization and usage. Thermal runaway is a notorious event where the overheating of the LIB results in a chain of events leading to the catastrophic failure of the device. Here, an in situ safety mechanism that shutdowns the LIB at critical temperatures before the onset of thermal runaway is developed. This is achieved by the deposition of thermal responsive polyethylene (PE) microspheres coated with multiwalled carbon nanotubes (CNTs) on electrodes via 3D printing. Rapid shutdown of LIB full cells under 60 s with ≈1 mg of additive is demonstrated. The mechanism of the shutdown is investigated through post‐mortem analysis of the heat‐treated cells that provides evidence of the formation of an insulating PE film that prevents ionic flow, disabling the LIB. Further, galvanostatic cycling of CNT‐coated PE‐loaded cells is used to demonstrate the advantages of the approach, where the precise and low loading of the conductive additive exhibits no impact on the full cell normal operation.