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Mild Upgrading of Bio‐Crude Pyrolysis Oil: A Concept Based on Bio‐Based Alcohols with Selective Water Adsorption
Author(s) -
Kumar Pazhavelikkakath Purushothaman Rajeesh,
Buntara Teddy,
Zhang Zheng,
Vehoff Ilse J.,
Boyadjian Cassia,
Falco Lorena,
Seshan Kulathuiyer,
Gómez Natalia,
Heeres Hero J.,
MeliánCabrera Ignacio
Publication year - 2018
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201700719
Subject(s) - pyrolysis , adsorption , oxygenate , catalysis , pyrolysis oil , raw material , chemical engineering , materials science , pulp and paper industry , acid value , biomass (ecology) , organic chemistry , waste management , chemistry , oceanography , engineering , geology
Biocrude pyrolysis oil is obtained by a process called fast‐pyrolysis, in which almost any organic‐based feedstock is thermally processed at moderate temperatures, in the range of 400–600 °C, in the absence of oxygen at short residence times. After condensing the vapors in a cooling tray, a dark‐brown bioliquid is obtained. The quality of the thus obtained fast pyrolysis oil has some barriers for its direct use as transportation fuel. Low caloric value, high viscosity, and corrosion are the major challenges for its implementation in conventional engines. There have been sustained efforts to improve the quality of the oil. In this Communication we are reporting a concept on improving the acidic properties by means of a combined catalysis and adsorption approach. We found that fast pyrolysis oil can be upgraded through alcoholysis using n ‐butanol and tetrahydrofurfuryl alcohol, which are biomass‐derived bulk chemicals. The reaction is acid catalyzed whereas water is continuously separated from the condensate mixture through molecular sieve adsorption. Under optimal conditions, the ultimate acidity and water content of the upgraded product are negligible.