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Hybrid Reduced Graphene Oxide/Manganese Diselenide Cubes: A New Electrode Material for Supercapacitors
Author(s) -
Balamuralitharan B.,
Karthick S. N.,
Balasingam Suresh Kannan,
Hemalatha K. V.,
Selvam Samayanan,
Raj J. Anandha,
Prabakar Kandasamy,
Jun Yongseok,
Kim HeeJe
Publication year - 2017
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201700097
Subject(s) - supercapacitor , diselenide , graphene , capacitance , manganese , materials science , oxide , electrochemistry , electrode , impurity , transition metal , chemical engineering , nanotechnology , inorganic chemistry , selenium , chemistry , catalysis , metallurgy , engineering , biochemistry , organic chemistry
The integration of 2 D graphene nanosheets and layered transition‐metal dichalcogenides has been recognized as one of the most extensive strategies for the synthesis of promising electrode materials for energy‐storage devices. In this study, cubic manganese diselenide (MnSe 2 ) and hybrid reduced graphene oxide/MnSe 2 (G‐MnSe 2 ) materials were synthesized by a facile hydrothermal method. Metallic selenium impurities are considered to be a major unwanted byproduct in this method. An effective means to remove such bulk chalcogenides is a key challenge. For the synthesis of the G‐MnSe 2 hybrid material, we used a strategy in which the graphene oxide was mixed with manganese and selenium precursors. Surprisingly, the final G‐MnSe 2 product contained a negligible amount of selenium impurity. The MnSe 2 and G‐MnSe 2 hybrid materials were characterized in detail. For the first time, the electrochemical energy‐storage behavior of MnSe 2 ‐based materials was assessed for supercapacitor applications. The specific capacitance of the MnSe 2 electrode was approximately 57.8 mF cm −2 , whereas the hybrid G‐MnSe 2 electrode showed a much higher specific capacitance of 93.3 mF cm −2 at a scan rate of 1 mV s −1 . A symmetric cell made from the G‐MnSe 2 hybrid material showed excellent long‐term stability for 4500 cycles and approximately 106 % retention of its initial capacitance, which is impressive compared with the cycle life of the MnSe 2 ‐based symmetric cell (80 % capacitance retention at the 4500th cycle).