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Solvothermal Synthesis of a Molybdenum Disulfide/Reduced Porous Graphene Oxide Nanocomposite as a High‐Performance Anode Material for Lithium‐Ion Batteries
Author(s) -
Bae Youngkuk,
Seong ChaeYong,
Yoo Suyeon,
Park SeungKeun,
Piao Yuanzhe
Publication year - 2017
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201600502
Subject(s) - graphene , materials science , molybdenum disulfide , anode , lithium (medication) , chemical engineering , nanocomposite , oxide , graphite oxide , graphite , electrode , nanoparticle , specific surface area , inorganic chemistry , nanotechnology , composite material , chemistry , organic chemistry , metallurgy , medicine , endocrinology , engineering , catalysis
Although molybdenum disulfide (MoS 2 ) has a higher theoretical capacity than graphite as an anode material for lithium‐ion batteries, its intrinsically poor electrical and ionic conductivity decrease its rate properties and lithium‐storage capacity. In this work, we prepared a MoS 2 /reduced porous graphene oxide (rPGO) composite by the solvothermal method to complement the conductivity and to improve the lithium‐storage properties of MoS 2 . PGO was synthesized by a convenient, low‐costing, and mass‐producible nitric acid treatment method. Owing to its large surface area and porous structure, the MoS 2 /rPGO sample exhibited improved capacity and cyclic stability over other MoS 2 /reduced graphene oxide (rGO) and MoS 2 nanoparticle samples. After 100 cycles, the MoS 2 /rPGO electrode showed an improved capacity of 932 mAh g −1 , whereas the capacity of the MoS 2 /rGO electrode was 395 mAh g −1 at a current density of 200 mA g −1 .