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Pretreatment of Graphite Anodes with Lithium Sulfate to Improve the Cycle Performance of Lithium‐Ion Batteries
Author(s) -
Cui Xiaoling,
Tang Fengjuan,
Li Chunlei,
Zhang Yu,
Wang Peng,
Li Shiyou,
Ye Xiushen
Publication year - 2017
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201600360
Subject(s) - lithium (medication) , graphite , materials science , electrolyte , electrode , dielectric spectroscopy , electrochemistry , x ray photoelectron spectroscopy , fourier transform infrared spectroscopy , chemical engineering , anode , lithium ion battery , analytical chemistry (journal) , composite material , battery (electricity) , chemistry , organic chemistry , medicine , engineering , endocrinology , power (physics) , physics , quantum mechanics
Abstract Graphite electrode surfaces are pretreated by spray‐deposition method with 0.5 mol L −1 Li 2 SO 4 aqueous solution. The physical and electrochemical properties of a solid electrolyte interphase (SEI) film formed on the surface of Li 2 SO 4 ‐treated graphite electrode are investigated by Fourier transform infrared spectroscopy, X‐ray photoelectron spectroscopy, and electrochemical measurements. The results show that the SEI film formed, promoted by Li 2 SO 4 , is thin, stable, effective, and elastic to accommodate volume changes of graphite electrode during electrochemical cycles. Due to the fact that the Li/mesophase carbon microbeads (MCMB) cell based on Li 2 SO 4 ‐treated graphite electrode exhibits excellent cycling performance and low interfacial impedance, we can deduce that such modifies have positive implications for lithium‐ion batteries (LIBs), offering the possibility of faster‐charging LIBs and LIBs that are suitable for rate‐demanding applications, such electric vehicles and hybrid electric vehicles.