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Self‐poled Efficient Flexible “Ferroelectretic” Nanogenerator: A New Class of Piezoelectric Energy Harvester
Author(s) -
Ghosh Sujoy Kumar,
Sinha Tridib Kumar,
Mahanty Biswajit,
Mandal Dipankar
Publication year - 2015
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201500167
Subject(s) - materials science , nanogenerator , piezoelectricity , energy harvesting , nanocomposite , optoelectronics , capacitor , dielectric , composite material , voltage , electrical engineering , energy (signal processing) , statistics , mathematics , engineering
Superior ferro‐ and piezo‐electret properties in a self‐poled, porous hybrid ferroelectretic polymer nanocomposite film for next‐generation device paradigms is introduced by in situ generation of platinum (Pt) nanoparticles (NPs) embedded in poly(vinylidenefluoride‐ co ‐hexafluoropropylene) P(VDF–HFP). The cooperative functionality between the self‐polarized β‐phase and the micropores as charge trapping sites is realized by using a simple solvent evaporation method. As a consequence, the resulting film exhibits extraordinary ferroelectretic behavior, as demonstrated by the superior electrical square‐shaped hysteresis loop with large remnant polarization ( P r ≈61.7 μC cm −2 ), piezoelectric charge coefficient ( d 33 ∼−686 pC N −1 ), and ultrahigh dielectric properties ( ε r =2678, tan δ =0.79 at 1 kHz). A new type of ferroelectretic nanogenerator (FTNG) is fabricated using a flexible hybrid nanocomposite film that effectively converts the applied mechanical energy into electrical energy upon compressive normal stress (e.g., by actuating with a human finger). The 18 V of the open‐circuit output voltage with expected 17.7 μA short‐circuit current are generated from the FTNG under 4 MPa of normal stress amplitude. The high piezoelectric energy conversion efficiency ( η piezo ≈0.2 %) of the FTNG shows that the hybrid polymer nanocomposite film is well suited for the next generation of piezoelectric‐based energy harvesters. The operation of more than 50 blue LEDs, 25 green LEDs, and several capacitors without any subsidiary batteries is demonstrated using the FTNG.