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Enhanced Catalytic Activity for Biodiesel Synthesis using an Acid‐Tolerant Calcium/Magnesium/Aluminum‐Oxide Hybrid with Improved Hydrophobicity and Dispersibility
Author(s) -
Fan Mingming,
Han Qiuju,
Zhang Pingbo,
Jiang Pingping
Publication year - 2015
Publication title -
energy technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.91
H-Index - 44
eISSN - 2194-4296
pISSN - 2194-4288
DOI - 10.1002/ente.201402165
Subject(s) - biodiesel , catalysis , coprecipitation , magnesium , biodiesel production , calcium oxide , transesterification , reusability , materials science , yield (engineering) , aluminium , thermal stability , chemical engineering , calcium , aluminum oxide , nuclear chemistry , chemistry , inorganic chemistry , organic chemistry , metallurgy , software , computer science , engineering , programming language
To increase the activity of the CaO catalyst for biodiesel synthesis, CaO–MgO–Al 2 O 3 was prepared by coprecipitation. CaO, CaO–MgO, and CaO–MgO–Al 2 O 3 were investigated with regard to their dispersibility, hydrophobicity, and thermal stability. The additions of MgO and Al 2 O 3 had a beneficial effect on the activity of the resulting CaO–MgO–Al 2 O 3 catalyst, showing a biodiesel yield of 97.7 % because of the improvements in dispersibility and hydrophobicity. CaO–MgO–Al 2 O 3 gave better acid resistance and better reusability, which is important for potential application in biodiesel production.

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