Open AccessNovel engineering of ruthenium‐based electrocatalysts for acidic water oxidation: A mini review
Author(s) -
Zhou Feng,
Zhang Lijie,
Li Juan,
Wang Qi,
Chen Yurou,
Chen Hailun,
Lu Guolong,
Chen Guang,
Jin Huile,
Wang Shun,
Wang Jichang
Publication year - 2021
Publication title -
engineering reports
Language(s) - English
Resource type - Journals
ISSN - 2577-8196
DOI - 10.1002/eng2.12437
Subject(s) - ruthenium , oxygen evolution , iridium , catalysis , materials science , water splitting , chemistry , kinetics , nanotechnology , chemical engineering , electrochemistry , organic chemistry , engineering , electrode , photocatalysis , physics , quantum mechanics
The oxygen evolution reaction (OER) is pivotally involved in proton exchange membrane water electrolyzers (PEMWEs). However, the commercialized iridium‐based catalysts often suffer from severe sluggish kinetics, eventually deteriorating the polarization and overall PEMWEs performance. Therefore, to develop OER electrocatalysts with promising reaction kinetics and high stability is of great significance for PEMWEs. Compared to iridium, the ruthenium‐based catalysts possess lower price and higher activity in acidic water oxidation, which promises Ru‐based materials to replace the state‐of‐the‐art IrO x . Yet, the less stable ruthenium than iridium impedes its real applications. In this mini review, recent knowledge of feasible engineering strategies for migrating the Ru‐based electrocatalysts' stability is summarized. In order to improve performance and durability, basic fundamentals of acidic OER on nanoscale and molecular engineered Ru‐based electrocatalysts are briefly introduced. In the end, the challenges and outlook for engineering novel Ru‐based electrocatalysts are presented.