Open AccessPerformance evaluation of graphene oxide–MnO 2 nanocomposite for alkaline membrane fuel cell
Author(s) -
Ahmed Mushtaq,
Ahmad Shahbaz,
Nawaz Tahir,
Durrani M. Ali,
Ali Asghar,
Saher Saim,
Khan Muhammad Alam Zaib,
Egilmez Mehmet,
Samreen Ayesha,
Mustafa Faisal
Publication year - 2022
Publication title -
electrochemical science advances
Language(s) - English
Resource type - Journals
ISSN - 2698-5977
DOI - 10.1002/elsa.202100085
Subject(s) - graphene , nanocomposite , materials science , nanorod , oxide , cathode , electrochemistry , chemical engineering , alkaline fuel cell , manganese , electrode , nanotechnology , inorganic chemistry , chemistry , electrolyte , metallurgy , engineering
The manganese dioxide/graphene oxide (MnO 2 /GO) nanocomposites were prepared from hydrothermally synthesized MnO 2 nanorods and graphene oxide. Electrocatalytic performance for the oxygen reduction reactions (ORR) of the fabricated MnO 2 /GO nanocomposites was evaluated using the rotating disk electrode (RDE) method. It is found that MnO 2 /GO nanocomposites deliver significantly enhanced performance compared to standalone MnO 2 and GO with current density and onset potential values of 5.1 mA/cm 2 and 0.93 V versus RHE, respectively. The alkaline membrane fuel cell (AMFC) characteristics were also studied. In particular, the single‐cell alkaline fuel cell stack with MnO 2 /GO nanocomposite as cathode loading produced a peak power density value of 82 mW/cm 2 . Our findings revealed great potential for MnO 2 /GO nanocomposites for their electrocatalytic performance and utilization in AMFC as the cathode. Namely, MnO 2 /GO achieved fuel cell functionalities that were comparable to the widely used commercial Pt/C. The enhanced electrochemical performance of MnO 2 /GO is attributed to the synergistic interaction between highly conductive GO sheets and active sites of MnO 2 nanorods. The commendable performance of MnO 2 /GO suggests that it can be used as electrocatalysts in alkaline fuel cell applications.